Question 

We have been separated since Nov. 2017. My wife ordered things in my name without my permission or knowledge until I received the bills in the mail in July 2018 from 2 mail order catalogs. The divorce is not finalized yet. During the time of the order I was never at the home.

Criminal Defense Lawyer, R. Christopher Simons Answer
You cannot charge her with anything. However, you can call the police to report a crime; then the prosecutor will decide whether or not to charge her.